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Applications of PLA to grow with new additive developments
Biopolymer reduces greenhouse gas emissions by 80-90%, does not contain persistent, bio-accumulative and toxic chemicals. The second conference on biopolymers was hosted by NatureWorks LLC. Among the highlights were sessions on Successful integration of Ingeo into existing manufacturing facilities, new product developments, blending and additive approaches to tailoring performance. Few of the highlights to Blending and Additive approaches discussed at the conference:Ningbo, China based Tianan Biologics Co. Ltd. currently has PHBV production capacity of about 2000 tpa. PHBV is a biodegradable, 100% renewable biopolymer made directly by the fermentation of glucose in Ralstonia eutropha bacteria. Compared to PLA, PHBV exhibits excellent heat resistance and low water vapor transmission rates (WVTR), but poor thermal melt stability. Two PHBV/PLA (30/70) and PHBV/ BASF EcoFlex formulations were described showing improved property profiles over the individual biopolymers.
Limitations in impact strength, heat resistance and tensile strength preclude PLA from many high performance engineered durable applications. Maki of RTP Company described a number of compounded biopolymer formulations (32-80% biocontent) as offsets to HIPS, PC/ABS, 30% glass fiber reinforced polypropylene or polyamide composites using PLA alloys or reinforced PLA to achieve notched Izod impact strength ranging from 2-16 ft lb/notch, up to 320°F HDT and 1.6 MM psi flexural modulus. RTP is currently working on several other specialized applications requiring antistatic, custom color, flame retardant, wear resistant, or electrically conductive end-use performance.
Teknor Apex Companys Anderson described thermoplastic starch (TPS) technology for the modification of PLA biopolymers. TPS can be made by compounding a variety of granulated starches, water and glycerol. TPS/PLA blends can be compounded via patented Teknor Apex technology for improved impact strength, melt strength and metal (mold) release behavior without detriment to biocontent or compostability. Plasticizer level is an effective means of modifying performance with maximum elongation and notched Izod impact strength found at about 36% glycerol, e.g., 200% and 4 ft lbs/in notch, respectively. MB 90000 (non-starch based) series provides improved melt strength or impact strength while maintaining excellent clarity. M20000 (starch based) series provides two levels of further strength improvement, but result in opaque products.
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Both formulations contain a combination of ca.10% talc, 10% plasticizer/crystallizing accelerant (dioctyl adipate) and 1.0% Takemoto aromatic sulfonate nucleating agent relative to the Ingeo polymer. Heat resistance is gained by the in-situ
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